Since we already have the balanced reaction, let's start by applying
M =
moles/L
0.320 M NaOH = x moles NaOH
/0.0342 L NaOH
= 0.01094 moles NaOH
Now, we use our reaction equation to do a mole to mole ratio
0.01094 moles NaOH
(1 mole H2SO4)3
/
(2 mole NaOH)
= 0.00547 moles H2SO4
We know both H2SO4 Molarity and moles, hence we can find L
0.186 M H2SO4
(0.00547 mole H2SO4)/
(L H2SO4)
= 0.0294 L H2SO4
The volume needed is 29.4 mL